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  <xsd:element id="pebo_FinancingReceivableAcquiredWithDeterioratedCreditQualityNetOfDeferredIncome" name="FinancingReceivableAcquiredWithDeterioratedCreditQualityNetOfDeferredIncome" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_FinancingReceivableAllowanceForCreditLossesNetRecoveriesWriteDowns" name="FinancingReceivableAllowanceForCreditLossesNetRecoveriesWriteDowns" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="credit" xbrli:periodType="duration" />
  <xsd:element id="pebo_FinancingReceivableModificationsNumberOfContractsDuringPeriod" name="FinancingReceivableModificationsNumberOfContractsDuringPeriod" nillable="true" substitutionGroup="xbrli:item" type="xbrli:integerItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_FinancingReceivableModificationsPostModificationRecordedInvestmentDuringPeriod" name="FinancingReceivableModificationsPostModificationRecordedInvestmentDuringPeriod" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="duration" />
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  <xsd:element abstract="true" id="pebo_GrossCoreDepositMember" name="GrossCoreDepositMember" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
  <xsd:element abstract="true" id="pebo_GrossCustomerRelationshipMember" name="GrossCustomerRelationshipMember" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesAccumulatedUnrecognizedHoldingGain" name="HeldToMaturitySecuritiesAccumulatedUnrecognizedHoldingGain" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesAccumulatedUnrecognizedHoldingLosses" name="HeldToMaturitySecuritiesAccumulatedUnrecognizedHoldingLosses" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="credit" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesContinuousUnrealizedLossPosition12MonthsOrLongerAccumulatedLoss" name="HeldToMaturitySecuritiesContinuousUnrealizedLossPosition12MonthsOrLongerAccumulatedLoss" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="credit" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesContinuousUnrealizedLossPositionLessThan12MonthsAccumulatedLoss" name="HeldToMaturitySecuritiesContinuousUnrealizedLossPositionLessThan12MonthsAccumulatedLoss" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="credit" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesDebtMaturitiesAverageYield" name="HeldToMaturitySecuritiesDebtMaturitiesAverageYield" nillable="true" substitutionGroup="xbrli:item" type="num:percentItemType" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesDebtMaturitiesNextRollingTwelveMonthsAmortizedCostBeforeOtherThanTemporaryImpairment" name="HeldToMaturitySecuritiesDebtMaturitiesNextRollingTwelveMonthsAmortizedCostBeforeOtherThanTemporaryImpairment" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesDebtMaturitiesNextRollingTwelveMonthsAverageYield" name="HeldToMaturitySecuritiesDebtMaturitiesNextRollingTwelveMonthsAverageYield" nillable="true" substitutionGroup="xbrli:item" type="num:percentItemType" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesDebtMaturitiesRollingAfterTenYearsAmortizedCostBeforeOtherThanTemporaryImpairment" name="HeldToMaturitySecuritiesDebtMaturitiesRollingAfterTenYearsAmortizedCostBeforeOtherThanTemporaryImpairment" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesDebtMaturitiesRollingAfterTenYearsAverageYield" name="HeldToMaturitySecuritiesDebtMaturitiesRollingAfterTenYearsAverageYield" nillable="true" substitutionGroup="xbrli:item" type="num:percentItemType" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesDebtMaturitiesRollingYearSixThroughTenAmortizedCostBeforeOtherThanTemporaryImpairment" name="HeldToMaturitySecuritiesDebtMaturitiesRollingYearSixThroughTenAmortizedCostBeforeOtherThanTemporaryImpairment" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesDebtMaturitiesRollingYearSixThroughTenAverageYield" name="HeldToMaturitySecuritiesDebtMaturitiesRollingYearSixThroughTenAverageYield" nillable="true" substitutionGroup="xbrli:item" type="num:percentItemType" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesDebtMaturitiesRollingYearTwoThroughFiveAmortizedCostBeforeOtherThanTemporaryImpairment" name="HeldToMaturitySecuritiesDebtMaturitiesRollingYearTwoThroughFiveAmortizedCostBeforeOtherThanTemporaryImpairment" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesDebtMaturitiesRollingYearTwoThroughFiveAverageYield" name="HeldToMaturitySecuritiesDebtMaturitiesRollingYearTwoThroughFiveAverageYield" nillable="true" substitutionGroup="xbrli:item" type="num:percentItemType" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesInUnrealizedLossPositionsQualitativeDisclosure12MonthsOrLongerNumberOfPositions" name="HeldToMaturitySecuritiesInUnrealizedLossPositionsQualitativeDisclosure12MonthsOrLongerNumberOfPositions" nillable="true" substitutionGroup="xbrli:item" type="xbrli:integerItemType" xbrli:periodType="instant" />
  <xsd:element id="pebo_HeldToMaturitySecuritiesInUnrealizedLossPositionsQualitativeDisclosureLessThan12MonthsNumberOfPositions" name="HeldToMaturitySecuritiesInUnrealizedLossPositionsQualitativeDisclosureLessThan12MonthsNumberOfPositions" nillable="true" substitutionGroup="xbrli:item" type="xbrli:integerItemType" xbrli:periodType="instant" />
  <xsd:element id="pebo_ImpairedFinancingReceivableFairValueDisclosure" name="ImpairedFinancingReceivableFairValueDisclosure" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_ImpairedFinancingReceivableOutstandingPrincipalBalanceMeasuredatFairValue" name="ImpairedFinancingReceivableOutstandingPrincipalBalanceMeasuredatFairValue" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element abstract="true" id="pebo_IncreaseDecreaseInStockByClassRollForward" name="IncreaseDecreaseInStockByClassRollForward" nillable="true" substitutionGroup="xbrli:item" type="xbrli:stringItemType" xbrli:periodType="duration" />
  <xsd:element abstract="true" id="pebo_InterestIncomeAbstract" name="InterestIncomeAbstract" nillable="true" substitutionGroup="xbrli:item" type="xbrli:stringItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_LoansReceivableAndLoansHeldForSaleFairValueDisclosure" name="LoansReceivableAndLoansHeldForSaleFairValueDisclosure" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element abstract="true" id="pebo_MidwestBancsharesInc.DepositsAcquiredMember" name="MidwestBancsharesInc.DepositsAcquiredMember" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
  <xsd:element abstract="true" id="pebo_MidwestBancsharesInc.LoansAcquiredMember" name="MidwestBancsharesInc.LoansAcquiredMember" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
  <xsd:element abstract="true" id="pebo_MidwestBancsharesInc.Member" name="MidwestBancsharesInc.Member" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
  <xsd:element abstract="true" id="pebo_NonEmployeeDirectorsMember" name="NonEmployeeDirectorsMember" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
  <xsd:element abstract="true" id="pebo_NotRatedMember" name="NotRatedMember" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_OtherComprehensiveIncomeLossNetOfReclassificationsAndTax" name="OtherComprehensiveIncomeLossNetOfReclassificationsAndTax" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="credit" xbrli:periodType="duration" />
  <xsd:element id="pebo_OtherComprehensiveIncomeLossReclassificationAdjustmentinNetIncomeNetofTax" name="OtherComprehensiveIncomeLossReclassificationAdjustmentinNetIncomeNetofTax" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="credit" xbrli:periodType="duration" />
  <xsd:element id="pebo_OtherComprehensiveIncomeLossSettlementandCurtailmentCostsofPensionandOtherPostretirementBenefitPlanValuationNetofTax" name="OtherComprehensiveIncomeLossSettlementandCurtailmentCostsofPensionandOtherPostretirementBenefitPlanValuationNetofTax" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="credit" xbrli:periodType="duration" />
  <xsd:element id="pebo_PensionandOtherPostretirementBenefitPlansAccumulatedOtherComprehensiveIncomeLossNetGainsLossesbeforeTaxbeforeSettlements" name="PensionandOtherPostretirementBenefitPlansAccumulatedOtherComprehensiveIncomeLossNetGainsLossesbeforeTaxbeforeSettlements" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="credit" xbrli:periodType="instant" />
  <xsd:element abstract="true" id="pebo_PerformanceBasedVestingMember" name="PerformanceBasedVestingMember" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
  <xsd:element abstract="true" id="pebo_PerformanceOfFairValueAgainstBookValueAxis" name="PerformanceOfFairValueAgainstBookValueAxis" nillable="true" substitutionGroup="xbrldt:dimensionItem" type="xbrli:stringItemType" xbrli:periodType="duration" />
  <xsd:element abstract="true" id="pebo_PerformanceOfFairValueAgainstBookValueDomain" name="PerformanceOfFairValueAgainstBookValueDomain" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_PledgedFinancialInstrumentsNotSeparatelyReportedAvailableForSaleSecuritiesForDepositsAndRepurchaseAgreements" name="PledgedFinancialInstrumentsNotSeparatelyReportedAvailableForSaleSecuritiesForDepositsAndRepurchaseAgreements" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_PledgedFinancialInstrumentsNotSeparatelyReportedAvailableForSaleSecuritiesForFederalHomeLoanBankAndFederalReserveBank" name="PledgedFinancialInstrumentsNotSeparatelyReportedAvailableForSaleSecuritiesForFederalHomeLoanBankAndFederalReserveBank" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_PledgedFinancialInstrumentsNotSeparatelyReportedHeldToMaturitySecuritiesForDepositsAndRepurchaseAgreements" name="PledgedFinancialInstrumentsNotSeparatelyReportedHeldToMaturitySecuritiesForDepositsAndRepurchaseAgreements" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_PledgedFinancialInstrumentsNotSeparatelyReportedHeldToMaturitySecuritiesForFederalHomeLoanBankAndFederalReserveBank" name="PledgedFinancialInstrumentsNotSeparatelyReportedHeldToMaturitySecuritiesForFederalHomeLoanBankAndFederalReserveBank" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_ScheduleOfFinancingReceivablesAcquiredWithDeterioratedCreditQualityTableTextBlock" name="ScheduleOfFinancingReceivablesAcquiredWithDeterioratedCreditQualityTableTextBlock" nillable="true" substitutionGroup="xbrli:item" type="nonnum:textBlockItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_ScheduleOfFinancingReceivablesTypeTableTextBlock" name="ScheduleOfFinancingReceivablesTypeTableTextBlock" nillable="true" substitutionGroup="xbrli:item" type="nonnum:textBlockItemType" xbrli:periodType="duration" />
  <xsd:element abstract="true" id="pebo_ScheduleOfNetBenefitCostsAbstract" name="ScheduleOfNetBenefitCostsAbstract" nillable="true" substitutionGroup="xbrli:item" type="xbrli:stringItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_ScheduleofPensionPlansRemeasurementandSettlementsTextBlock" name="ScheduleofPensionPlansRemeasurementandSettlementsTextBlock" nillable="true" substitutionGroup="xbrli:item" type="nonnum:textBlockItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisableIntrinsicValue" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisableIntrinsicValue" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisableNumber" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisableNumber" nillable="true" substitutionGroup="xbrli:item" type="xbrli:sharesItemType" xbrli:periodType="instant" />
  <xsd:element id="pebo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisableWeightedAverageExercisePrice" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisableWeightedAverageExercisePrice" nillable="true" substitutionGroup="xbrli:item" type="num:perShareItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisableWeightedAverageRemainingContractualTerms" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsExercisableWeightedAverageRemainingContractualTerms" nillable="true" substitutionGroup="xbrli:item" type="xbrli:durationItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsOutstandingIntrinsicValue" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsOutstandingIntrinsicValue" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="instant" />
  <xsd:element id="pebo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsVestedAndExpectedToVestExercisableNumber" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsVestedAndExpectedToVestExercisableNumber" nillable="true" substitutionGroup="xbrli:item" type="xbrli:sharesItemType" xbrli:periodType="instant" />
  <xsd:element id="pebo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsVestedAndExpectedToVestExercisableWeightedAverageRemainingContractualTerms" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsVestedAndExpectedToVestExercisableWeightedAverageRemainingContractualTerms" nillable="true" substitutionGroup="xbrli:item" type="xbrli:durationItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsVestedInPeriodTotalIntrinsicValue" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardEquityInstrumentsOtherThanOptionsVestedInPeriodTotalIntrinsicValue" nillable="true" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType" xbrli:balance="debit" xbrli:periodType="duration" />
  <xsd:element id="pebo_Sharesauthorizedunder2006EquityPlan" name="Sharesauthorizedunder2006EquityPlan" nillable="true" substitutionGroup="xbrli:item" type="xbrli:sharesItemType" xbrli:periodType="instant" />
  <xsd:element abstract="true" id="pebo_TimeBasedVestingMember" name="TimeBasedVestingMember" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_TreasuryStockReleasedFromRestrictionsDueToExpiration" name="TreasuryStockReleasedFromRestrictionsDueToExpiration" nillable="true" substitutionGroup="xbrli:item" type="xbrli:sharesItemType" xbrli:periodType="duration" />
  <xsd:element id="pebo_TroubledDebtRestructuringsduringprior12monthsthatsubsequentlydefaultedTableTextBlock" name="TroubledDebtRestructuringsduringprior12monthsthatsubsequentlydefaultedTableTextBlock" nillable="true" substitutionGroup="xbrli:item" type="nonnum:textBlockItemType" xbrli:periodType="duration" />
  <xsd:element abstract="true" id="pebo_USTreasurySecuritiesAndUSGovernmentAgenciesDebtSecuritiesMember" name="USTreasurySecuritiesAndUSGovernmentAgenciesDebtSecuritiesMember" nillable="true" substitutionGroup="xbrli:item" type="nonnum:domainItemType" xbrli:periodType="duration" />
</xsd:schema>


